【新要闻】1400小时超长待机 我科学家破译锌溴液流电池长寿命“密码”

Core Insights - The research team from Dalian Institute of Chemical Physics has made significant progress in the development of a new bromine-based flow battery system, achieving a proof of concept for long-life zinc-bromine flow batteries, with results published in the journal Nature Energy [2][4]. Group 1: Technology Development - The new bromine-based flow battery relies on a two-electron transfer reaction system, which enhances energy density and reduces corrosion issues associated with traditional single-electron transfer methods [3][4]. - By introducing amine compounds as bromine scavengers in the electrolyte, the team successfully converted generated Br into brominated amine compounds, significantly lowering the concentration of Br in the solution [3][4]. Group 2: Performance Metrics - In tests of a scaled-up 5kW system, the zinc-bromine flow battery demonstrated stable operation for over 700 cycles at a current density of 40 mA cm-2, with a total lifespan exceeding 1400 hours and an energy efficiency of over 78% [4]. - The low concentration of Br resulted in no corrosion of key materials such as current collectors, electrodes, and membranes before and after cycling, confirming the non-corrosive nature of the electrolyte [4]. Group 3: Implications for Future Applications - This research provides a new approach for the design of long-life bromine-based flow batteries, laying the groundwork for further applications and commercialization of zinc-bromine flow batteries [4].