双氧水

Search documents
中石化双氧水生产技术突破国外封锁 在欧美实施技术许可
Yang Shi Wang· 2025-07-04 01:22
Core Viewpoint - Sinopec has achieved a significant breakthrough in the development of fluidized bed hydrogen peroxide production technology, breaking the long-standing foreign monopoly and providing technological support for the upgrade of domestic hydrogen peroxide production technology [1][2]. Group 1: Technology Development - The fluidized bed hydrogen peroxide production technology developed by Sinopec has been in research for 15 years, resulting in 72 Chinese invention patents and 1 PCT international patent [1]. - The new technology integrates multiple innovations, including three types of catalysts, three process enhancements, and two new reactions, significantly improving production efficiency [1]. - The fluidized bed process allows for large-scale equipment, meeting the production needs for projects like caprolactam and propylene oxide [1]. Group 2: Market Position and Production Capacity - In 2022, China held over 50% of the global hydrogen peroxide market share, with an annual production capacity of 24 million tons, although the production process mainly relied on outdated fixed bed technology [1]. - The first domestic industrial production unit using Sinopec's fluidized bed technology was established in Hunan in 2018, with a capacity of 72,000 tons per year, outperforming domestic technology standards [2]. - In 2024, Hunan Petrochemical is expected to produce a total of 58,500 tons of hydrogen peroxide, with the first half of the year showing a cumulative production of 318,600 tons and a significant reduction in comprehensive energy consumption year-on-year [2]. Group 3: Industry Impact and Future Prospects - Experts at a recent conference recognized that Sinopec's hydrogen peroxide technology effectively addresses the inherent safety issues in hydrogen peroxide production, indicating its potential for industry-wide adoption [2]. - The technology has already been licensed to foreign companies, with a major European engineering firm responsible for promoting its licensing in Europe and North America [1].
柳化股份: 柳化股份关于上海证券交易所对公司2024年年度报告信息披露监管问询函的回复公告
Zheng Quan Zhi Xing· 2025-06-30 16:34
Core Viewpoint - LiuZhou Chemical Co., Ltd. has received an inquiry letter from the Shanghai Stock Exchange regarding its 2024 annual report, prompting the company to provide detailed responses about its operational status, profitability, and future strategies to enhance sustainable operations [1][2]. Group 1: Operational Status - The company primarily engages in the production and sale of hydrogen peroxide, with reported revenues of 140 million, 142 million, and 165 million yuan over the past three years [2]. - The company has a designed annual production capacity of 160,000 tons for 27.5% hydrogen peroxide, but after recent changes, it can only rely on a single production line with a capacity of 100,000 tons per year [2]. - The production output for 27.5% hydrogen peroxide from 2022 to 2024 was 122,700 tons, 125,800 tons, and 169,200 tons, reflecting year-on-year increases of 20.3%, 2.57%, and 34.5% respectively [2]. Group 2: Profitability Analysis - The revenue from 27.5% hydrogen peroxide was 137 million yuan with a gross margin of 22.42%, an increase of 3.45 percentage points year-on-year [5]. - The revenue from 50% hydrogen peroxide was 25 million yuan, but its gross margin decreased to 15.97%, down 6.46 percentage points year-on-year [5]. - The average selling price of 27.5% hydrogen peroxide in 2024 was 935.07 yuan per ton, a decrease of 3.96% compared to the previous year, while the unit production cost decreased by 8.05% to 725.39 yuan per ton [8]. Group 3: Future Strategies - The company plans to enhance its operational capabilities by maximizing the use of existing facilities, increasing technical upgrades, and diversifying its product offerings to improve profitability [4]. - The company aims to explore markets for electronic-grade and food-grade hydrogen peroxide products to further diversify its revenue streams [4]. - LiuZhou Chemical is also looking to adapt to new regulations and policies to facilitate its transformation and upgrade, while seeking suitable assets and strategic investors for long-term development [4].
中国石化流化床双氧水技术迭代升级
Zhong Guo Hua Gong Bao· 2025-06-30 02:35
Core Viewpoint - China Petrochemical Corporation (Sinopec) has successfully developed a proprietary fluidized bed hydrogen peroxide production technology, breaking through foreign technological barriers and supporting the upgrade of China's hydrogen peroxide production technology [1][2] Group 1: Technology Development - The fluidized bed hydrogen peroxide production technology has been licensed to foreign companies and is represented by the largest engineering company in Europe for technology licensing in Europe and the United States [1] - The new technology integrates multiple innovations, including three types of catalysts, three process enhancements, and two new reactions, significantly improving production efficiency and enabling large-scale production [1] Group 2: Market Position - In 2022, China accounted for over 50% of the global hydrogen peroxide market share, with an annual production capacity of 24 million tons [1] - The production process primarily relied on outdated fixed bed technology, which had a production efficiency less than one-fourth that of the foreign fluidized bed technology, highlighting the need for technological breakthroughs [1] Group 3: Industrial Application - Hunan Petrochemical, utilizing Sinopec's proprietary fluidized bed hydrogen peroxide production technology, established the first domestic industrial production facility with a capacity of 72,000 tons per year in 2018, achieving operational stability and surpassing domestic technical standards [2] - The hydrogen peroxide produced is a crucial raw material for the newly constructed caprolactam facility, with two large-scale hydrogen peroxide production units being built as part of the project [2] Group 4: Performance Metrics - In 2024, Hunan Petrochemical's two hydrogen peroxide production units are expected to produce a total of 585,000 tons, with performance metrics meeting design specifications [2] - From January to May of the current year, the units produced 345,000 tons of hydrogen peroxide, with comprehensive energy consumption decreasing by 2.43 kg of standard oil per ton compared to the previous year [2]
双氧水行业安全提升呼唤工艺升级
Zhong Guo Hua Gong Bao· 2025-06-09 02:01
Industry Overview - The hydrogen peroxide production capacity in China is rapidly expanding, with 122 existing acid-base alternating fixed bed production units, which pose significant safety risks due to the potential for hydrogen peroxide decomposition and explosions [1] - The Ministry of Emergency Management has issued guidelines to eliminate the acid-base alternating process and prioritize the use of fluidized bed technology to enhance the inherent safety of hydrogen peroxide production [1] Technological Innovations - Jiangsu Zhongxu Technology Co., Ltd. has developed over 60 proprietary technologies for hydrogen peroxide production, successfully transferring more than 70 units domestically and internationally [2] - The company has replaced the traditional acid-base alternating process with a fully acidic fixed bed process, which operates in a weakly acidic environment, significantly reducing the risk of hydrogen peroxide decomposition and explosions [2] - The new process also features a comprehensive protective system and full automation, improving production safety, efficiency, and reducing waste and material consumption [2] Research and Development - China National Chemical Corporation and Tsinghua University have collaborated to develop a micro-reactor technology for enhancing the anthraquinone method of hydrogen peroxide production, achieving a 100% conversion rate of hydrogen and oxygen [2] - The core reactor's size has been reduced to one-tenth of traditional reactors, with minimal or no tail gas emissions, and a pilot test for continuous production at a scale of hundreds of tons has been completed [2] - The research team is working on designing modular distributed production units and developing process packages for larger-scale studies [2] Key Components - Alkyl anthraquinone is a critical element in the anthraquinone method for hydrogen peroxide production, influencing technological advancements [3] - The research team at Sinopec Petroleum and Chemical Research Institute has identified the solubility and stability issues of anthraquinone, leading to the development of a new high-performance anthraquinone structure through alkylation-oxidation methods [3] - This new anthraquinone shows significantly improved solubility and stability compared to pentyl anthraquinone, with plans for industrialization and platform technology development [3]