直接甲醇燃料电池
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富电子铂镍钴催化剂破解甲醇燃料电池中毒溶解难题
Ke Ji Ri Bao· 2025-10-17 06:43
Core Insights - The research team led by Miao Zhengpei at Hainan University has developed an electron-rich titanium nitride-mediated platinum-nickel-cobalt alloy catalyst, addressing key challenges in the practical application of direct methanol fuel cells, such as carbon monoxide poisoning and the dissolution of transition metals [1][2] Group 1: Catalyst Development - The new catalyst demonstrates significant performance improvements in actual devices by utilizing titanium nitride as a support, which enhances the electronic structure and reduces the binding strength between platinum and carbon monoxide, thereby increasing the catalyst's resistance to poisoning [2] - The optimized electronic environment also strengthens the chemical bonds between platinum and nickel, cobalt, significantly suppressing the dissolution of transition metal elements [2] Group 2: Performance Metrics - In accelerated durability tests, the dissolution rate of nickel and cobalt in the new electron-rich catalyst is reduced by over 50% compared to commercially available carbon-supported platinum-nickel-cobalt alloy catalysts [2] - Membrane electrode assembly tests show that the new catalyst operates continuously for 50 hours at a current density of 100 mA/cm² with only 9.6% voltage decay, achieving a peak power density retention of 89.3%, indicating nearly four times the stability compared to the commercial counterpart [2] Group 3: Broader Implications - This research lays a scientific foundation for the development of efficient and durable catalysts for direct methanol fuel cells and offers new research directions for other electrochemical energy systems affected by poisoning and corrosion, such as proton exchange membrane fuel cells and formic acid fuel cells [2]