锌溴液流电池
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大化所开发溴基液流电池新体系
Zhong Guo Hua Gong Bao· 2025-12-26 03:22
Core Insights - A new bromine-based two-electron transfer reaction system has been developed, enabling the concept validation and system scaling of long-life zinc-bromine flow batteries [1][2] - The new reaction significantly improves energy density and reduces corrosion, addressing key challenges in traditional bromine flow battery systems [1][2] Group 1: Research and Development - The research team, led by Li Xianfeng from the Dalian Institute of Chemical Physics, has published their findings in the journal Nature Energy [1] - The new bromine flow battery relies on the redox reaction between bromide ions (Br-) and bromine (Br2), which has advantages such as abundant resources, high electrode potential, and high solubility [1] Group 2: Technical Innovations - The introduction of amine compounds as bromine scavengers effectively lowers the concentration of bromine in the electrolyte, enhancing battery performance [1] - The dual-electron transfer method from Br- to Br+ (brominated amine compounds) significantly increases the energy density of the battery [1] Group 3: Performance Metrics - In a scaled-up 5 kW system test, the battery demonstrated stable operation for over 700 cycles at 40 mA/cm², with a total lifespan exceeding 1400 hours and an energy efficiency of over 78% [2] - The extremely low concentration of bromine resulted in no corrosion of key materials such as current collectors, electrodes, and membranes before and after cycling, confirming the non-corrosive nature of the electrolyte [2] Group 4: Implications for Industry - This research provides a new approach for the design of long-life bromine flow batteries, laying the groundwork for further applications and promotion of zinc-bromine flow batteries [2]
【新要闻】1400小时超长待机 我科学家破译锌溴液流电池长寿命“密码”
Ke Ji Ri Bao· 2025-12-24 02:50
Core Insights - The research team from Dalian Institute of Chemical Physics has made significant progress in the development of a new bromine-based flow battery system, achieving a proof of concept for long-life zinc-bromine flow batteries, with results published in the journal Nature Energy [2][4]. Group 1: Technology Development - The new bromine-based flow battery relies on a two-electron transfer reaction system, which enhances energy density and reduces corrosion issues associated with traditional single-electron transfer methods [3][4]. - By introducing amine compounds as bromine scavengers in the electrolyte, the team successfully converted generated Br into brominated amine compounds, significantly lowering the concentration of Br in the solution [3][4]. Group 2: Performance Metrics - In tests of a scaled-up 5kW system, the zinc-bromine flow battery demonstrated stable operation for over 700 cycles at a current density of 40 mA cm-2, with a total lifespan exceeding 1400 hours and an energy efficiency of over 78% [4]. - The low concentration of Br resulted in no corrosion of key materials such as current collectors, electrodes, and membranes before and after cycling, confirming the non-corrosive nature of the electrolyte [4]. Group 3: Implications for Future Applications - This research provides a new approach for the design of long-life bromine-based flow batteries, laying the groundwork for further applications and commercialization of zinc-bromine flow batteries [4].
我科学家破译锌溴液流电池长寿命“密码”
Ke Ji Ri Bao· 2025-12-22 01:02
Core Insights - The research team at Dalian Institute of Chemical Physics has made significant progress in developing a new bromine-based flow battery system, achieving proof of concept for long-life zinc-bromine flow batteries [1][2] Group 1: Research Developments - The team successfully developed a novel bromine two-electron transfer reaction system, which addresses the corrosion issues associated with traditional bromine flow batteries [2] - The new system utilizes amine compounds as bromine scavengers, converting generated Br2 into brominated amine compounds, effectively reducing Br2 concentration in the electrolyte [2] Group 2: Performance Metrics - The zinc-bromine flow battery demonstrated stable operation for over 700 cycles under 40 mA cm-2 conditions, with a total lifespan exceeding 1400 hours and an energy efficiency of over 78% [2]
1400小时超长待机 我科学家破译锌溴液流电池长寿命“密码”
Ke Ji Ri Bao· 2025-12-20 07:42
Core Insights - The research team led by Li Xianfeng from the Dalian Institute of Chemical Physics has made significant progress in the development of a new bromine-based flow battery system, achieving proof of concept for long-life zinc-bromine flow batteries and scaling up the system [1][4] Group 1: Technology Development - The new bromine-based flow battery relies on a dual electron transfer reaction system, which effectively reduces the concentration of bromine ions (Br) in the electrolyte, thereby enhancing the battery's energy density and lifespan [2][3] - By introducing amine compounds as bromine scavengers in the bromine electrolyte, the team has successfully converted generated Br into brominated amine compounds, significantly lowering the corrosiveness of the electrolyte [2] Group 2: Performance Metrics - In tests scaled to a 5kW system, the zinc-bromine flow battery demonstrated stable operation for over 700 cycles at a current density of 40 mA cm-2, with a total lifespan exceeding 1400 hours and an energy efficiency of over 78% [3] - The use of a low-cost and less corrosion-resistant SPEEK membrane did not affect the battery's performance, as no corrosion was observed in key materials such as current collectors, electrodes, and membranes after cycling [3] Group 3: Implications for Future Applications - This research provides a new approach for designing long-life bromine-based flow batteries, laying the groundwork for further applications and commercialization of zinc-bromine flow batteries [4]
助力能源转型 校企协同共研锌溴液流电池储能技术
Ren Min Wang· 2025-09-23 02:19
Core Insights - The 2025 China Flow Battery Energy Storage Conference and Exhibition (CFE2025) commenced in Wuhan, focusing on advancements in flow battery technology and its industrialization pathways [1] - Junan Energy, a leading company in zinc-bromine flow battery industrialization, showcased its core technology that ensures safety and longevity, with a cycle life of 10,000 times and a lifespan exceeding 20 years [1] - The global energy transition is accelerating, with energy storage technology becoming a crucial link between renewable and traditional energy sources, supported by national policies emphasizing long-duration energy storage [1] Company Developments - Junan Energy has achieved full-chain industrialization from materials to systems through a collaboration with Wuhan University of Technology, which includes a demonstration project integrating photovoltaic generation, zinc-bromine flow battery storage, and charging stations [2] - The company has developed a product matrix covering large-scale storage, commercial storage, and household storage, with ongoing research aimed at reducing size and costs for broader applications in various sectors [2]
2024年中国长时储能液流电池新增装机2.43GWh,同比增长834.6%
起点锂电· 2025-06-27 09:40
Core Viewpoint - The article discusses the upcoming 2025 Fifth Electric Vehicle Battery Swap Conference and the growth of long-duration energy storage, particularly focusing on flow batteries and their market potential in China. Group 1: Event Details - The event theme is "Swap Battery City, Smart Two-Wheelers" and will take place on July 10-11, 2025, at the Shenzhen Baoan DENGXILU International Hotel [2] - The event is sponsored by various companies including Yadi Technology Group, Tailing Group, and others, indicating strong industry support [2] Group 2: Market Growth and Projections - In 2024, China's newly installed capacity of long-duration energy storage flow batteries is expected to reach 2.43 GWh, a year-on-year increase of 834.6% [2] - The projected new installed capacity for long-duration energy storage flow batteries in 2025 is 5.6 GWh, representing a year-on-year growth of 130.5% [3] Group 3: Technology and Cost Trends - The average bid price for long-duration energy storage flow battery systems (≥ 4h) in 2024 is 2.11 RMB/Wh, a decrease of approximately 20% from 2023 [5] - By 2026, the average bid price is expected to drop below 2.0 RMB/Wh, and by 2030, it may fall below 1.0 RMB/Wh [5] Group 4: Emerging Business Models - The introduction of an electrolyte leasing model has been noted, which can reduce initial investment costs by over 20% for projects [5] - The "flow + lithium" hybrid storage model is gaining traction, combining the rapid response of lithium batteries with the long-duration capacity of flow batteries [8] Group 5: Industry Trends - The trend of companies expanding overseas is becoming significant as the domestic new energy storage market becomes increasingly competitive [9] - The establishment of a closed-loop economy for vanadium resources is being developed, integrating raw materials, new materials, and new energy [8]