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材料新突破!科学家将绝缘体变成半导体
半导体芯闻· 2025-06-16 10:13
Core Viewpoint - A groundbreaking discovery from the University of Michigan reveals that a new type of silicone resin can function as a semiconductor, challenging the long-held belief that silicone materials are merely insulators [3][9]. Group 1: Semiconductor Properties - The new silicone copolymer exhibits semiconductor properties, enabling applications in flexible electronics, new display technologies, and wearable sensors [3][5]. - Traditional semiconductors are rigid, while silicone resins offer the potential for flexible electronic products that can display various colors [5]. Group 2: Molecular Structure and Conductivity - The molecular structure of organic silicone consists of alternating silicon and oxygen atoms (Si—O—Si), with organic groups attached to the silicon atoms. Cross-linking of polymer chains leads to various three-dimensional structures, altering physical properties [7]. - The discovery of the copolymer's conductivity potential arose from the interaction of electrons through overlapping Si—O—Si bonds, allowing for charge flow [7]. Group 3: Color Spectrum and Light Emission - The semiconductor characteristics of silicone copolymers allow for a rich color spectrum, with electron transitions between ground and excited states determining light emission [8]. - Researchers demonstrated the relationship between chain length and light absorption/emission by arranging copolymers of varying lengths in test tubes, resulting in a rainbow effect under UV light [8].
芯片研究,新突破
半导体行业观察· 2025-03-30 02:56
Core Viewpoint - The research from the RIKEN Center for Emergent Matter Science indicates that inserting potassium ions between layers of molybdenum disulfide can transform its electronic properties, allowing it to behave as a metal, superconductor, or insulator [1][3]. Group 1: Material Properties - Molybdenum disulfide (MoS2) can be separated into thin crystals with different electronic phases, specifically 2H (semiconductor) and 1T (metal) [3]. - The introduction of potassium ions can switch the material's phase from 2H to 1T, with a ratio of approximately two potassium ions for every five molybdenum atoms [3]. Group 2: Superconductivity Discovery - The research team observed superconductivity in the 1T phase of MoS2 when potassium ions were introduced and the sample was cooled to -268°C, which was an unexpected finding [3][4]. - Previous observations of superconductivity in the 2H phase were known, but the occurrence in the 1T phase at different temperatures was surprising [3]. Group 3: Insulating Phase - When potassium ions were allowed to leak from the 1T MoS2 until a lower ion concentration was reached, the material transitioned from a metal to an insulator at -193°C [4]. - This unexpected transition highlights the potential of using potassium ion insertion as a method to control the structure and properties of two-dimensional materials like MoS2 [4]. Group 4: Research Implications - The findings suggest that the method of introducing potassium ions could lead to the discovery of new superconductors and enhance the understanding of electronic phases in materials [4]. - The research team has been developing this method for the past decade, indicating its significance in exploring new electronic properties [4].