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巴斯夫已布局!刷屏的“诺奖”MOF材料,一文读懂
DT新材料· 2025-10-08 16:04
Core Viewpoint - The awarding of the 2025 Nobel Prize in Chemistry to Susumu Kitagawa, Richard Robson, and Omar M. Yaghi for their development of Metal-Organic Frameworks (MOFs) signifies a major recognition for the new materials sector, potentially accelerating the industrialization of MOFs [2] Group 1: MOFs Overview - MOFs, or Metal-Organic Frameworks, are porous compounds formed by metal ions or clusters and organic ligands, exhibiting unique structural properties and high application potential [3][5] - Since their inception in the 1990s, over 100,000 types of MOFs have been synthesized, although naming conventions vary across research teams [5] Group 2: Structural Characteristics and Advantages - MOFs possess a highly porous structure with porosity exceeding 90%, allowing for significant molecular adsorption capabilities, making them suitable for applications in gas separation, catalysis, and drug delivery [8] - The structural tunability of MOFs enables customization of properties such as porosity and crystallinity through formulation adjustments, enhancing their functional applications [9] Group 3: Synthesis Methods - Various synthesis methods for MOFs have been developed, including mechanochemical, hydrothermal, and spray-drying methods, with mechanochemical and spray-drying methods showing the most promise for large-scale production [10][12] Group 4: Applications of MOFs - MOFs are widely used in gas storage, separation, and adsorption due to their tunable pore sizes, making them ideal for capturing gases like hydrogen and carbon dioxide [15][16] - They can also serve as electrode materials and battery separators, enhancing the performance of energy storage devices like lithium-ion and lithium-sulfur batteries [18] - MOFs have applications in water purification and recovery, demonstrating high adsorption capacities for dissolved metal ions and enabling water extraction from air in arid regions [20] - Additionally, MOFs are utilized in drug delivery systems and as sensors, benefiting from their high surface area and tunable structures for targeted therapeutic applications [21]
多孔MOFs破局之路:金属有机框架获诺奖加持,产业化进程与中国机遇
材料汇· 2025-10-08 15:51
Core Viewpoint - The Nobel Prize in Chemistry awarded to pioneers in Metal-Organic Frameworks (MOFs) highlights the significant potential of these materials in various applications, marking a transition from laboratory research to industrialization, particularly in China, which is rapidly advancing in this field [2][4]. Group 1: Challenges and Breakthroughs in MOFs Industrialization - The industrialization of MOFs faces three core challenges: cost and scalability, stability and lifespan, and shaping and processing [6][7]. - For cost and scalability, breakthroughs include green synthesis methods that significantly reduce production costs and the implementation of continuous flow production technologies to ensure consistent quality [7][8]. - To address stability and lifespan, advancements in molecular design and composite reinforcement have been made, enhancing the structural stability of MOFs under industrial conditions [9]. - The challenge of shaping and processing is being tackled by developing techniques to convert MOFs from powder to usable components, such as membranes and granules for industrial applications [10]. Group 2: Overview of Chinese MOFs Industry - A competitive landscape of Chinese companies is emerging, with a complete industrial ecosystem covering upstream, midstream, and downstream sectors [13]. - Key players in the adsorption and separation sector include Jiangsu Jiutian High-Tech Co., which leads in MOF separation membranes, and Shandong Namede New Materials, a top supplier of scaled MOF materials [14]. - In the energy and environment sector, companies like Yueyang Xingchang Petrochemical are exploring MOF applications in solid-state batteries, while Sinopec and Baowu Steel are testing MOFs for carbon capture [15]. - The biomedical and frontier applications sector is represented by Shanghai Boxiu New Materials, focusing on drug delivery systems, and Beijing Huake Furu Technology, developing MOF-based biosensors [16]. Group 3: Future Outlook for China's MOFs Industry - The recognition from the Nobel Prize is expected to catalyze further investment and policy support for the MOFs industry in China [18]. - China possesses the largest research teams, a complete chemical industry chain, a significant domestic market, and proven industrialization capabilities, positioning it for a potential boom in the MOFs sector by 2028-2030 [19]. - The anticipated growth will not only lead to increased production capacity but also to innovations in applications, establishing China as a leader in the global MOFs market [19].