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三氟乙酸(TFA)
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现在的雨水不一样了,该为此担忧吗?
Hu Xiu· 2025-09-20 09:38
Core Insights - The article discusses the increasing presence of trifluoroacetic acid (TFA) in various environmental samples, including rainwater, lakes, rivers, and even human blood and urine, indicating a global trend of rising TFA concentrations [1][2][3]. Group 1: Environmental Impact - TFA levels in the leaves and needles of various tree species in Germany have increased by 5 to 10 times over the past 40 years [2]. - TFA is classified as a "forever chemical" due to its strong carbon-fluorine bonds, which make it resistant to natural degradation [3]. - The United Nations Environment Programme (UNEP) has assessed TFA's risk since 1998, concluding that its current risk is minimal, at least until 2100, although this assessment may be re-evaluated in 2024 [7][10]. Group 2: Regulatory Actions - Germany has proposed to classify TFA as a reproductive toxin and a highly stable substance, with public consultations ending on July 25, 2024 [10]. - European environmental scientists have expressed concerns that rising TFA levels could pose irreversible harm and have called for a broad ban on all PFAS, including TFA [11]. - Some countries, including Denmark and Minnesota, have begun to take action against pesticides that generate TFA, with Denmark announcing a ban on such pesticides by July 2025 [57]. Group 3: Sources of TFA - TFA enters the environment through various pathways, including the use of TFA in biological research and its release from industrial processes in agriculture, pharmaceuticals, and precision chemicals [15][16]. - The primary source of TFA in rainwater is attributed to the release of fluorinated gases, such as refrigerants, which can decompose and produce TFA [17][20]. - Research indicates that TFA may also be naturally generated in the ocean, with estimates suggesting that oceanic TFA could range from 60 million to 200 million tons [25][26]. Group 4: Health Concerns - Current studies suggest that TFA does not exhibit acute toxicity, with some researchers comparing its toxicity to that of table salt [39]. - However, there is growing evidence that TFA may have biological effects, including lowering lipid and cholesterol levels in mice [41]. - Concerns have been raised about TFA's potential impact on ecosystems, with studies indicating that TFA can accumulate in plants and affect soil pH levels [44][50]. Group 5: Future Directions - Researchers agree that more long-term toxicological data on TFA is needed to understand its effects fully and to identify all sources of TFA [52]. - The introduction of new fluorinated gases, such as HFOs, may lead to increased TFA production, prompting calls for the rapid phase-out of these substances [54][56]. - Ongoing debates among researchers and regulatory bodies highlight the urgency of addressing TFA emissions and their potential environmental and health impacts [59].
两大化工巨头,再关停、出售
DT新材料· 2025-09-19 16:04
Group 1: Solvay's Strategic Changes - Solvay will terminate the production of selected product lines at its Bad Wimpfen plant, specifically stopping the production of trifluoroacetic acid (TFA) and related organic compounds by early 2026, which will result in a reduction of approximately 100 jobs [1][2] - The Bad Wimpfen plant will see new investments aimed at establishing a state-of-the-art NocolokⓇ paste and coating facility, consolidating its position as a global innovation and customer application center in automotive brazing [2] - Solvay plans to allocate around €250 million for restructuring and strategic investments around 2026, reaffirming Germany's importance as an industrial base [3] Group 2: SK Group's Divestment and Strategic Focus - SK Group is selling its entire 35% stake in the Sinopec-SK (Wuhan) Petrochemical Company for approximately 819.3 billion KRW (around 4.17 billion RMB), as the joint venture has accumulated losses exceeding 1 trillion KRW due to oversupply and intensified price competition in the Chinese ethylene market [4][5] - The joint venture, established in 2013 with a total investment of 3.3 trillion KRW, was once a symbol of SK's localization strategy in China, producing 3.2 million tons of general chemicals annually [4] - SK Group is accelerating its restructuring efforts to raise new funds, including plans to divest its overseas businesses, which were acquired for a total of approximately $600 million [5] - The company is shifting its focus towards the "ABC" strategy, concentrating on artificial intelligence, batteries, and chips, with a commitment to invest 8.2 trillion KRW in these growth areas by 2030 [6]