二氧化碳资源化利用

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全新催化剂让二氧化碳合成对二甲苯
Ke Ji Ri Bao· 2025-06-17 01:31
Group 1 - A new catalyst has been developed by researchers from Anhui University of Technology and other institutions, enabling the direct synthesis of para-xylene from carbon dioxide and hydrogen, breaking the world record for production efficiency of such catalysts [1][2] - Para-xylene (PX) is a critical raw material for producing chemical products, with an annual demand in China exceeding 30 million tons. The traditional production method relies on processing heavy oil, which is energy-intensive and generates high emissions [1] - The new method utilizes renewable energy to produce hydrogen, which is then reacted with carbon dioxide to manufacture PX, offering a greener alternative to conventional high-energy and high-emission production processes [1] Group 2 - The newly developed "metal oxide-molecular sieve" composite catalyst operates in two parts: the metal oxide facilitates the reaction between carbon dioxide and hydrogen to form simple olefins, while the molecular sieve assembles these olefins into the final PX product [2] - The molecular sieve has been designed with a unique "capsulation" approach to minimize impurities in the final product, resulting in unprecedented production efficiency, with over 1 kilogram of PX produced per kilogram of catalyst in a day [2] - The design concept of the composite catalyst is considered universal, with potential applications in other reaction systems that utilize carbon dioxide and hydrogen to produce high-value chemical products, enabling customized production [2]
中国科学家提出合成化工产品关键原料新工艺
Huan Qiu Wang Zi Xun· 2025-06-11 09:19
Core Viewpoint - A new composite catalyst developed by a research team at Anhui University successfully synthesizes para-xylene directly from carbon dioxide and hydrogen, setting a world record for single-pass space-time yield [1][2] Group 1: Catalyst Development - The new composite catalyst consists of metal oxides and molecular sieves, designed to enhance the selectivity for para-xylene through a "capsule" design and surface passivation to prevent side reactions [1] - The catalyst achieves a single-pass space-time yield of 1000.8 grams of para-xylene using 1000 grams of catalyst over one day, significantly surpassing existing performance levels reported in scientific literature [2] Group 2: Industry Impact - Para-xylene is a critical raw material for producing polyester fibers, coatings, and dyes, with China's annual demand exceeding 30 million tons [1] - Traditional methods for synthesizing para-xylene are energy-intensive and environmentally harmful, consuming approximately 4 tons of oil and emitting about 3 tons of carbon dioxide for every ton produced [1] - The new method utilizing renewable energy for hydrogen production and direct synthesis from carbon dioxide offers a sustainable alternative to conventional high-energy, high-emission processes [1]
环氧丙烷破局:向高附加值转型
Zhong Guo Hua Gong Bao· 2025-06-10 02:59
Core Insights - The Chinese propylene oxide (PO) industry is facing a contradiction where capacity growth outpaces demand, necessitating a shift towards high value-added products as a core strategy for industry breakthrough [1][2] - The Ministry of Industry and Information Technology has emphasized the importance of enhancing the value chain in the fine chemical industry, aiming to develop specialized and innovative products to improve competitiveness [2] Group 1: Industry Challenges and Directions - China's PO capacity is projected to reach 7.47 million tons per year by 2024, accounting for nearly one-third of global capacity, with a self-sufficiency rate of 96% [2] - The apparent consumption of PO in China is estimated at approximately 5.9 million tons in 2024, leading to a classification of PO as a high-risk product by the China Petroleum and Chemical Industry Federation [2] - The industry is encouraged to pursue "incremental innovation" and "stock optimization" to address the challenges posed by rapid capacity expansion [3] Group 2: Incremental Innovation Strategies - Incremental innovation involves developing non-polyurethane products such as high-purity propylene glycol and electronic-grade solutions, which are crucial for sectors like semiconductors and display panels [3][5] - The Ministry of Industry and Information Technology's 2024 edition of the "Guidance Catalog for First Application Demonstration of Key New Materials" highlights support for advanced semiconductor materials, including high-purity chemical reagents [3] Group 3: Stock Optimization Approaches - Stock optimization focuses on enhancing the production of polyether polyols, which are essential for polyurethane materials, in response to the growing demand for high-performance and environmentally friendly products [4] - Innovative technologies, such as the synthesis of polycarbonate diol from carbon dioxide and propylene oxide, have been developed to create biodegradable materials with significant market potential [4] - Companies are encouraged to adjust production layouts based on regional market demands and resource endowments to enhance competitiveness and reduce costs [4] Group 4: Technological Advancements - Various technologies have been successfully implemented to improve the synthesis of PO derivatives, addressing issues of high energy consumption and costs [5][6] - Key innovations include the development of solid catalysts to replace corrosive liquid catalysts, enhancing catalyst utilization, and implementing energy-saving techniques in distillation processes [5][6] - The industry is poised for further breakthroughs in green and energy-efficient processes, contributing to sustainable development in the petrochemical sector [6]